Titelbild: Directed Assembly of Inorganic Polyoxometalate-based Micrometer-Scale Tubular Architectures by Using Optical Control (Angew. Chem. 51/2012)
نویسندگان
چکیده
منابع مشابه
Directed assembly of inorganic polyoxometalate-based micrometer-scale tubular architectures by using optical control.
The self-assembly of supramolecular architectures to produce functional systems and devices is a key goal where molecular design, self-assembly, and materials design need to be combined together. In polyoxometalate chemistry we have taken the challenge to understand the assembly of clusters from the molecular to the nanoscale, by using a range of approaches including control of the available sp...
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متن کاملAssembly of inorganic [Mo2S2O2]2+ panels connected by selenite anions to nanoscale chalcogenide–polyoxometalate clusters
We describe how supramolecular assembly, mediated by control of the ratio of the hetero-atoms in the units [Mo2S2O2] 2+ and SeO3 2 leads to the formation of new types of building blocks, [(Mo2O2S2)3(OH)4(H2O)6(SeO3)] 1⁄4 {Mo6} and [(Mo2O2S2)2(OH)2(H2O)4(SeO3)] 1⁄4 {Mo4} which are linked in an type of inorganic ‘panelling’ to the assembly of a range of new clusters 1–3 with the general formula {...
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2012
ISSN: 0044-8249
DOI: 10.1002/ange.201209131